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  • Miniemulsion copolymerization of (meth)acrylates in the presence of functionalized multiwalled carbon nanotubes for reinforced coating applications.

Miniemulsion copolymerization of (meth)acrylates in the presence of functionalized multiwalled carbon nanotubes for reinforced coating applications.

Beilstein journal of nanotechnology (2017-07-12)
Bertha T Pérez-Martínez, Lorena Farías-Cepeda, Víctor M Ovando-Medina, José M Asua, Lucero Rosales-Marines, Radmila Tomovska
ABSTRACT

Film forming, stable hybrid latexes made of methyl metacrylate (MMA), butyl acrylate (BA) and 2-hydroxyethyl methacrylate (HEMA) copolymer reinforced with modified multiwalled carbon nanotubes (MWCNTs) were synthesized by in situ miniemulsion polymerization. The MWCNTs were pretreated by an air sonication process and stabilized by polyvinylpyrrolidone. The presence of the MWCNTs had no significant effect on the polymerization kinetics, but strongly affected the polymer characteristics (

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Octadecyl acrylate, contains 200 ppm monomethyl ether hydroquinone as inhibitor, 97%
Sigma-Aldrich
6-Benzylaminopurine hydrochloride, suitable for plant cell culture, ≥98%