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Rhodium-catalyzed C-H bond arylation of arenes.

Topics in current chemistry (2010-01-01)
Jean Bouffard, Kenichiro Itami
ABSTRACT

A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.

MATERIALS
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Product Description

Sigma-Aldrich
Rhodium, powder, 99.95% trace metals basis