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Merck

Occurrence of 2-ethylhexanoic acid in foods packed in glass jars.

Food additives and contaminants (2004-09-17)
S Elss, L Grünewald, E Richling, P Schreier
ABSTRACT

After simultaneous distillation-extraction (SDE) of commercial baby foods (n = 20) and fruit juices (n = 15) (among them 15 and eight products labelled 'organic', respectively) from 11 different suppliers, analyses performed by coupled capillary gas chromatography-mass spectrometry (GC-MS) revealed the presence of 2-ethylhexanoic acid (2-EHA), a known teratogenic compound. 2-EHA was found in 80 and 73% of the baby foods and fruit juices, respectively. Amounts ranged from 0.25 to 3.2 mg kg(-1)(average, 0.55 mg kg(-1)) and from 0.01 to 0.59 mg l(-1) (average, 0.18 mg l(-1)) in baby foods and fruit juices, respectively. GC-MS analysis of the SDE extracts obtained from the plastic gaskets inside the metal lids of the samples under study revealed the gaskets to be the origin of 2-EHA. As shown from the non-contaminated samples under study, obviously technology is available to avoid 2-EHA contamination of glass jar-packed food.

MATERIALS
Product Number
Brand
Product Description

Supelco
2-Ethylhexanoic acid, analytical standard
Sigma-Aldrich
2-Ethylhexanoic acid, 99%
Sigma-Aldrich
2-Ethylhexanoic acid, ≥99%