- Palladium-catalyzed cross-coupling reaction of alkenyl bromides with potassium alkyltrifluoroborates.
Palladium-catalyzed cross-coupling reaction of alkenyl bromides with potassium alkyltrifluoroborates.
Tetrahedron (2008-01-16)
Gary A Molander, Jungyeob Ham, Dave G Seapy
PMID18196177
RESUMEN
The Suzuki-Miyaura-type cross-coupling reaction of potassium alkyltrifluoroborates with various alkenyl bromides in the presence of 10 mol % of PdCl(2)(dppf)·CH(2)Cl(2) and 3.0 equiv of Cs(2)CO(3) in aqueous toluene at 80 °C provided the desired compounds in 49-95% yields. A variety of functional groups in the potassium alkyltrifluoroborates were tolerated under the basic conditions.
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