23182
(+)-1-(9-Fluorenyl)ethyl chloroformate solution
≥18 mM in acetone, for chiral derivatization, LiChropur™
Sinónimos:
(+)-FLEC solution
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About This Item
Fórmula empírica (notación de Hill):
C16H13ClO2
Número de CAS:
Peso molecular:
272.73
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NA.22
Productos recomendados
grade
for chiral derivatization
Quality Level
product line
ChiraSelect™
optical purity
enantiomeric ratio: ≥99.0:1.0 (HPLC)
quality
LiChropur™
concentration
≥18 mM in acetone
technique(s)
HPLC: suitable
refractive index
n20/D 1.359
storage temp.
2-8°C
InChI
1S/C16H13ClO2/c1-10(19-16(17)18)15-13-8-4-2-6-11(13)12-7-3-5-9-14(12)15/h2-10,15H,1H3
InChI key
SFRVOKMRHPQYGE-UHFFFAOYSA-N
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General description
(+)-1-(9-Fluorenyl)ethyl chloroformate [(+)-FLEC] is a chiral derivatizing reagent. It helps in separating enantiomers of α-amino acids, as well as helps in determining its optical purity using HPLC method.
Application
(+)-FLEC may be used in enantioselective analysis of glufosinate using reversed-phase high-performance liquid chromatography system coupled with a fluorescence detection system.
Physical form
Solución en 10 mL de Acetona
Other Notes
Agente derivatizante quiral para aminoácidos primarios y secundarios y aminas. Sus derivados son separados por LC de fase reversa y detección por fluorescencia para su determinación de pureza enantiomérica
Legal Information
ChiraSelect is a trademark of Sigma-Aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
3 - Flammable liquids
wgk_germany
WGK 2
flash_point_f
1.4 °F
flash_point_c
-17 °C
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Separation of enantiomers of a-hydroxy acids by reversed-phase liquid chromatography after derivatization with 1-(9-fluorenyl) ethyl chloroformate.
Fransson, Bengt, and Ulf Ragnarsson.
Journal of Chromatography A, 827, 31-36 (1998)
E Frigerio et al.
Journal of chromatography. A, 660(1-2), 351-358 (1994-02-04)
A sensitive and selective high-performance liquid chromatographic method for the determination of reboxetine enantiomers in human plasma was developed. Although two chiral centres are present in reboxetine, its stereospecific synthesis leads to two rather than four possible enantiomers. After extraction
Y Bergqvist et al.
Journal of chromatography, 652(1), 73-81 (1994-01-14)
A sensitive, stereoselective and rapid reversed-phase liquid chromatographic method for the determination of (SR)- and (RS)-mefloquine enantiomers in 100 microliters plasma and capillary blood collected on chromatographic paper is presented. The assay involves protein precipitation from plasma, liquid-liquid extraction of
K C Chan et al.
Electrophoresis, 16(4), 504-509 (1995-04-01)
Direct enantiomeric separations of some racemic amino acids derivatized with 9-fluorenylmethyl chloroformate were obtained using cyclodextrin-modified micellar electrokinetic chromatography (CD/MEKC) with a buffer made up of 5 mM sodium borate (pH 9.2), 150 mM sodium dodecyl sulfate (SDS) and 40
J Sukbuntherng et al.
Journal of analytical toxicology, 19(3), 139-147 (1995-05-01)
To study the disposition kinetics of methamphetamine (MAP), we have developed a sensitive high-performance liquid chromatographic (HPLC) assay to quantitate the enantiomers of MAP and its major metabolites, amphetamine (AP), p-hydroxymethamphetamine (p-OH-MAP), and p-hydroxyamphetamine (p-OH-AP), the latter two of which
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