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Sigma-Aldrich

1-Butylimidazole

98%

Sinónimos:

1-Butyl-1H-imidazole, 1-n-Butylimidazole, N-(n-Butyl)imidazole, N-Butyl-1H-imidazole, N-Butylimidazole, N-Butylimidazolium

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About This Item

Fórmula empírica (notación de Hill):
C7H12N2
Número de CAS:
4316-42-1
Peso molecular:
124.18
Beilstein/REAXYS Number:
109499
EC Number:
224-335-9
MDL number:
MFCD00042753
UNSPSC Code:
12352005
PubChem Substance ID:
24861574
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.480 (lit.)

bp

114-116 °C/12 mmHg (lit.)

density

0.945 g/mL at 25 °C (lit.)

SMILES string

CCCCn1ccnc1

InChI

1S/C7H12N2/c1-2-3-5-9-6-4-8-7-9/h4,6-7H,2-3,5H2,1H3

InChI key

MCMFEZDRQOJKMN-UHFFFAOYSA-N

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General description

1-Butylimidazole acts as an N-coordinated ligand. 1-Butylimidazole is formed as intermediate during the synthesis of a cationic cyclodextrin, used in the chiral separation of amino acids and anionic pharmaceuticals by capillary electrophoresis. Influence of 1-butylimidazole as base on the synthesis of dissymmetric chlorohydrin ester has been reported.

Application

1-Butylimidazole may be used in the synthesis of a heterocyclic mesomeric betaine. It was used in the synthesis of 1-(1-butyl-3-imidazolio)propane-3-sulfonate (BIm3S).

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

hcodes

H314,H330

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Dam. 1 - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

293.0 °F

flash_point_c

145 °C

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

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Joseph M Keane et al.
Journal of the American Chemical Society, 126(21), 6806-6815 (2004-05-27)
A series of metal complexes was synthesized in which arenes were dihapto-coordinated to pi-basic metal fragments having the general form [TpM(pi-acid)(L)], where Tp = hydridotris(pyrazolyl)borate, M = rhenium, molybdenum, or tungsten, pi-acid = CO or NO(+), and L = 1-methylimidazole
Kunakorn Chumnum et al.
Polymers, 13(3) (2021-02-13)
The self-healing composites were prepared from the combination of bromobutyl rubber (BIIR) and natural rubber (NR) blends filled with carbon nanotubes (CNT) and carbon black (CB). To reach the optimized self-healing propagation, the BIIR was modified with ionic liquid (IL)
A Crockard et al.
Journal of cerebral blood flow and metabolism : official journal of the International Society of Cerebral Blood Flow and Metabolism, 2(1), 67-72 (1982-01-01)
Autoregulation of cerebral blood flow (CBF) to mean arterial blood pressure (MABP) of 40-50 mm Hg has been demonstrated in the spontaneously breathing gerbil anaesthetised with barbiturate (60 mg/kg). CO2 reactivity has also been assessed at 2.8% change CBF/mm Hg
Carmen Solarte et al.
Molecules (Basel, Switzerland), 16(3), 2065-2074 (2011-03-04)
The anticipated worldwide increase in biodiesel production will result in an accumulation of glycerol for which there are insufficient conventional uses. The surplus of this by-product has increased rapidly during the last decade, prompting a search for new glycerol applications.
Nina Gonsior et al.
Beilstein journal of organic chemistry, 8, 390-397 (2012-04-18)
The synthesis of a heterocyclic mesomeric betaine by quaternization reaction of 1-butylimidazole and tetrabromo-1,4-benzoquinone is presented. The structure was verified by means of X-ray single-crystal analysis, NMR and IR spectroscopy. Inclusion complexes of the heterocyclic mesomeric betaine with randomly methylated
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