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Regioselective copolymerization of acryl sucrose monomers.

The Journal of organic chemistry (2004-10-23)
Maria Teresa Barros, Krasimira T Petrova, Ana Maria Ramos
ABSTRACT

1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
N,N-Dimethylformamide, anhydrous, 99.8%
Sigma-Aldrich
4-(Dimethylamino)pyridine, ReagentPlus®, ≥99%
Sigma-Aldrich
tert-Butyl(chloro)diphenylsilane, 98%
Sigma-Aldrich
Tetrabutylammonium iodide, reagent grade, 98%
Sigma-Aldrich
Sucrose, BioXtra, ≥99.5% (GC)