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Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Dalton transactions (Cambridge, England : 2003) (2007-11-07)
Isabelle Aillaud, Jacqueline Collin, Jérôme Hannedouche, Emmanuelle Schulz
ABSTRACT

The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.

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