698989

Poly(3-hexylthiophene-2,5-diyl)

regioregular, electronic grade, 99.995% trace metals basis, average M_n 15,000-45,000

• Synonym(s): Plexcore OS 1100, P3HT
• Linear Formula: (C₁₀H₁₄S)_n
• CAS Number: 156074-98-5
• MDL number: MFCD00217686

Properties

• grade: electronic grade
• assay: 99.995% trace metals basis
• form: solid
• mol wt: average M_n 15,000-45,000
• description: (>95% head-to-tail regioregular (HNMR))
• mp: 238 °C
• solubility: chloroform, trichlorobenzene, chlorobenzene, toluene, and xylenes: soluble
• fluorescence: λ_ex 450 nm; λ_em 575 nm
• Orbital energy: HOMO 5 eV ; LUMO 3 eV
• OPV Device Performance: ITO/NiO/P3HT/PC61BM/LiF/Al;
  • Short-circuit current density (J_sc): 11.3 mA/cm²
  • Open-circuit voltage (V_oc): 0.64 V
  • Fill Factor (FF): 0.69
  • Power Conversion Efficiency (PCE): 5.16 %
  ; ITO/PEDOT:PSS/P3HT:PC61BM (1:08)/Al;
  • Short-circuit current density (J_sc): 9.5 mA/cm²
  • Open-circuit voltage (V_oc): 0.63 V
  • Fill Factor (FF): 0.68
  • Power Conversion Efficiency (PCE): 5 %
• PDI: ≤2
• semiconductor properties: P-type (mobility=10⁻⁴ - 10⁻¹ cm²/V·s)

Description

General description

Poly(3-hexylthiophene) (P3HT) is a regioregular semiconducting polymer. It is used in organic electronics primarily because of its regular end-to-end arrangement of side chain, which allows efficient Π-Π stacking of the conjugated backbones. On account of the alkyl side group, P3HT is rendered hydrophobic in neutral state.

HOMO level 5.1 eV

Application

Polmer-based Materials for Printed Electronics: Enabling High Efficency Solar Power and Lighting

High purity P3HT for organic electronics research. Material optimized for use in active layers of OFETs and other devices. Poly(3-hexylthiophene-2,5-diyl) may be used extensively as a semiconducting layer in organic thin film field effect transistor (FETs) and solar cells.,2

Packaging

250 mg in poly bottle

1, 5 g in glass bottle

Legal Information

Product of Plextronics, Inc. U.S. Patent 6,166,172.

Plexcore is a registered trademark of Plextronics, Inc.