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533203

Sigma-Aldrich

2-(2-Hydroxy-5-methylphenyl)benzotriazole

97%

Synonym(s):
2-(2H-Benzotriazol-2-yl)-p-cresol
Empirical Formula (Hill Notation):
C13H11N3O
CAS Number:
Molecular Weight:
225.25
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

reaction suitability

reaction type: C-C Bond Formation

mp

125.5-129.5 °C (lit.)

SMILES string

Cc1ccc(O)c(c1)-n2nc3ccccc3n2

InChI

1S/C13H11N3O/c1-9-6-7-13(17)12(8-9)16-14-10-4-2-3-5-11(10)15-16/h2-8,17H,1H3

InChI key

MCPKSFINULVDNX-UHFFFAOYSA-N

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Related Categories

Application

Intermediate reactant in the synthesis of UV light absorbers for polyester fibers

Reactant for synthesis of:
  • Benzotriazole UV absorbers with a blocked hydroxy group for us in UV curable paint
  • Maleimide-bound benzotriazole monomer to use for emulsion polymerization

Used in:
  • Microstereophotolithography and shape memory alloy for fabrication of miniaturized actuators
  • PVS and wood / PVC composites as a stabilizer
  • Acrylonitrile-butadiene-styrene as a UV absorber

Packaging

25 g in glass bottle

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Chronic 1 - Skin Sens. 1B

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Certificate of Origin

B Björkner et al.
American journal of contact dermatitis : official journal of the American Contact Dermatitis Society, 8(1), 6-7 (1997-03-01)
A case of contact allergy to the UV absorber Tinuvin P is described in a patient with gingivitis who was previously treated with a dental restorative material. With high-performance liquid chromatography analysis, the presence of Tinuvin P could be shown
K L Kompa et al.
Proceedings of the National Academy of Sciences of the United States of America, 98(2), 410-414 (2001-02-24)
We propose a scheme for molecule-based information processing by combining well-studied spectroscopic techniques and recent results from chemical dynamics. Specifically it is discussed how optical transitions in single molecules can be used to rapidly perform classical (Boolean) logical operations. In
Rosa María Claramunt et al.
Molecules (Basel, Switzerland), 12(9), 2201-2214 (2007-10-27)
2-(2,4-Dimethylphenyl)-2H-benzotriazole (1) has been synthesized in a three step procedure starting from 2,4-dimethyl-N-(2-nitrophenyl)benzamide via a 5-(2,4- dimethylphenyl)-1-(2-nitrophenyl)-1H-tetrazole intermediate. Its structure and those of Tinuvin P and 2-phenyl-2H-benzotriazole (5) have been studied by multinuclear NMR (1H-, 13C- and 15N-) in solution
Allergic contact dermatitis from an ostomy bag.
E van Hecke et al.
Contact dermatitis, 18(2), 121-122 (1988-02-01)
K Arisu et al.
Contact dermatitis, 26(5), 311-316 (1992-05-01)
We report a 54-year-old female with allergic contact dermatitis from 2-(2-hydroxy-5-methylphenyl)benzotriazole (Tinuvin P) in a spandex tape sewn into underwear. Tinuvin P is used as an ultraviolet light absorber for stabilizing plastics and the other organic materials against discoloration and

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