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295647

Sigma-Aldrich

Phosphine

electronic grade, ≥99.9995%

Linear Formula:
PH3
CAS Number:
Molecular Weight:
34.00
EC Number:
MDL number:
PubChem Substance ID:

grade

electronic grade

Quality Level

vapor density

1.15 (vs air)

assay

≥99.9995%

form

gas

impurities

<1 ppm Argon (Ar)
<1 ppm Arsine (AsH3)
<1 ppm Carbon dioxide (CO2)
<1 ppm Carbon monoxide (CO)
<1 ppm Methane (CH4)
<1 ppm Nitrogen (N2)
<1 ppm Oxygen (O2)
<1 ppm Water (H2O)

bp

−87.5 °C (lit.)

transition temp

critical temperature 51.3 °C

application(s)

agriculture
environmental

SMILES string

P

InChI

1S/H3P/h1H3

InChI key

XYFCBTPGUUZFHI-UHFFFAOYSA-N

General description

Phosphine is an organophosphorus compound that can be used as a ligand with electronic and steric properties. It can be incorporated into the semiconductor to tune the crystallinity and composition of the nanocrystals by enhancing their photoconductive properties.
Atomic number of base material: 15 Phosphorus

Application

Phosphine may be used to modify the n-type single walled carbon nanotubes(SWCNTs) for the development of flexible thermoelectric materials. It may also be used as a catalyst in the preparation of cyclobuteno(60)fullerenes which finds potential applications in n-type organic semiconductor.
Phosphine is used primarily in the manufacture of III-IV semiconductor materials by OMCVD and as a dopant in crystalline and amorphous silicon.
Precursor to III-V semiconductor thin films. Also useful as a dopant for crystalline and amorphous silicon.

Packaging

10, 50 g in stainless steel cylinder

Recommended products

Stainless steel regulators Z527416 or Z527424 are recommended.

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Aquatic Acute 1 - Eye Dam. 1 - Flam. Gas 1A - Press. Gas Liquefied gas - Self-heat. 1 - Skin Corr. 1B

Storage Class Code

2A - Gases

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Certificate of Origin

Catherine Gomez et al.
The Journal of organic chemistry, 78(4), 1488-1496 (2013-01-25)
The phosphine-promoted [3 + 2] cyclizations between γ-substituted allenoates and arylideneoxindoles have been applied to the stereoselective synthesis of spiro(cyclopentene)oxindoles with trisubstituted cyclopentene units. It has been demonstrated that PPh(3) operates a very efficient control of the relative stereochemistry of
Ramandeep Kaur et al.
Journal of economic entomology, 106(5), 2259-2266 (2013-11-15)
Phosphine resistance alleles might be expected to negatively affect energy demanding activities such as walking and flying, because of the inverse relationship between phosphine resistance and respiration. We used an activity monitoring system to quantify walking of Rhyzopertha dominica (F.)
Mingren Shi et al.
Pest management science, 69(9), 1049-1060 (2013-01-08)
Control of pests in stored grain and the evolution of resistance to pesticides are serious problems worldwide. A stochastic individual-based two-locus model was used to investigate the impact of two important issues, the consistency of pesticide dosage through the storage
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), 42(1), 277-291 (2012-11-02)
Adducts of a number of tertiary pnicogen ligands ER(3) (triphenyl-phosphine and -arsine (PPh(3),AsPh(3)), diphenyl,2-pyridylphosphine (PPh(2)py), tris(4-fluorophenyl)phosphine (P(C(6)H(4)-4F)(3)), tris(2-tolyl)phosphine (P(o-tol)(3)), tris(cyclohexyl)phosphine (PCy(3))), with silver(I) thiocyanate, AgSCN are structurally and spectroscopically characterized. The 1:3 AgSCN : ER(3) complexes structurally defined (for PPh(3),AsPh(3) (diversely solvated))
Phosphine-Initiated Cation Exchange for Precisely Tailoring Composition and Properties of Semiconductor Nanostructures: Old Concept, New Applications.
Gui J, et al.
Angewandte Chemie (International Edition in English), 127(12), 3754-3758 (2015)

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