Ionic Liquid Stabilized Gelatin-Lignin Films: A Potential UV-Shielding Material with Excellent Mechanical and Antimicrobial Properties.

Significant research is currently underway to develop environmentally friendly UV-shielding materials. Herein, we have constructed choline citrate (a biobased ionic liquid, IL) stabilized homogeneous gelatin-lignin UV-shielding films with excellent antimicrobial and mechanical properties. The synthesis procedure of the films is less energy demanding, one pot, and sustainable in nature. Prepared films were characterized by mechanical and thermal analysis using UTM and TGA, respectively. ATR-IR and PXRD was employed to explore the possible formation of H-bonding between biopolymers and the IL and the change in crystallinity in films after addition of IL to the gelatin-lignin matrix. Surface morphology of prepared films has been studied using optical microscope, AFM, and field emission SEM (FE-SEM). Optical properties of prepared films were measured using UV/Vis spectroscopy. Antimicrobial activity of the prepared films was tested against Bacillus subtilis. Prepared biofilms showed a sun-protection factor (SPF) of up to ≈45.0, large elongation ≈200 %, and tensile strength ≈70 MPa, which are as good as those values exhibited by organic polymeric films, indicating a promising renewable-resources-based material for UV light blocking.