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Merck
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文件

179787

Sigma-Aldrich

丁基甲基醚

reagent grade, ≥98%

同義詞:

MTBE, 甲基叔丁基醚

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About This Item

線性公式:
(CH3)3COCH3
CAS號碼:
分子量::
88.15
Beilstein:
1730942
EC號碼:
MDL號碼:
分類程式碼代碼:
12352112
PubChem物質ID:
NACRES:
NA.07

等級

reagent grade

品質等級

蒸汽密度

3.1 (vs air)

蒸汽壓力

14.78 psi ( 55 °C)
4.05 psi ( 20 °C)

化驗

≥98%

形狀

liquid

自燃溫度

705 °F

expl. lim.

15.1 %

雜質

≤0.0005% peroxides (as H2O2)
≤0.1% water (Karl Fischer)

折射率

n20/D 1.369 (lit.)

bp

55-56 °C (lit.)

mp

-110 °C

密度

0.74 g/mL at 25 °C (lit.)

SMILES 字串

COC(C)(C)C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

InChI 密鑰

BZLVMXJERCGZMT-UHFFFAOYSA-N

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一般說明

tert-Butyl methyl ether is a commonly used organic solvent. It can be synthesized by acid catalyzed reaction between methanol and isobutene. It is an effective alternative to lead containing additives for enhancing the octane rating of gasoline.

應用

tert-Butyl methyl ether may be used to synthesize fatty acid methyl esters (FAMEs) and glycerol tert-butyl ether via transesterification with canola oil under supercritical conditions. Its addition during the polymerization of propene by stopped-flow method increases the number of active sites.

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-18.4 °F - closed cup

閃點(°C)

-28 °C - closed cup


分析證明 (COA)

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Relative solubility, stability, and absorptivity of lutein and β-carotene in organic solvents.
Craft NE and Soares JH.
Journal of Agricultural and Food Chemistry, 40(3), 431-434 (1992)
New approach of catalyst-free biodiesel production from canola oil in supercritical tert-butyl methyl ether (MTBE).
Farobie O, et al.
Fuel: The Science and Technology of Fuel and Energy, 135, 172-181 (2014)
Role of tert-Butyl Methyl Ether (TBME) as an External Donor in Propene Polymerization with Dibutyl Phthalate (DBP)-Containing MgCl2-Supported Ti Catalysts Activated with Al(i-C4H9)3.
Ohnishi R and Konakazawa T.
Macromolecular Chemistry and Physics, 205(14), 1938-1947 (2004)
Removal of methyl tert-butyl ether (MTBE) with Nafion.
Lien HL and Zhang WX
Journal of Hazardous Materials, 144(1), 194-199 (2007)
Eagleson M.
Concise Encyclopedia Chemistry, 154-154 (1994)

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