665096

三氯氧代 [（二甲基硫醚）三苯基膦氧化物] 铼 (V)

97%

• 同義詞: Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
• 經驗公式（希爾表示法）: C₂₀H₂₁Cl₃O₂PReS
• CAS號碼: 108695-90-5
• 分子量：: 648.98
• MDL號碼: MFCD08276862
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24884712
• NACRES: NA.22

屬性

• 化驗: 97%
• 形狀: powder
• 反應適用性: core: rhenium; reagent type: catalyst
• SMILES 字串: CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3
• InChI 密鑰: GIBDGLAUIKUJJX-UHFFFAOYSA-K

描述

應用

Catalyst for:

• Enantioselective reduction of ketones and imines
• Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
• Synthesis of 2-deoxy-α glycosides
• Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves