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Key Documents

447145

Sigma-Aldrich

硼烷二甲基硫醚络合物 溶液

5.0 M in diethyl ether

同義詞:

BMS, 三氢 [硫代双 [甲烷]] 硼

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About This Item

線性公式:
(CH3)2S · BH3
CAS號碼:
分子量::
75.97
Beilstein:
3663489
MDL號碼:
分類程式碼代碼:
12352112
PubChem物質ID:
NACRES:
NA.22

反應適用性

reagent type: reductant

濃度

5.0 M in diethyl ether

bp

~34 °C

密度

0.789 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI 密鑰

RMHDLBZYPISZOI-UHFFFAOYSA-N

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應用

用作区域选择性还原剂的反应物

涉及的反应物:
  • 硼氢化/氧化
笼状化合物的合成
Borane dimethyl sulfide complex can be used in the preparation of:
  • An amine-based polymer for CO2 uptake.
  • Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
  • Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 1

閃點(°F)

-31.0 °F - closed cup

閃點(°C)

-35 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


分析證明 (COA)

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Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification
Mason CR, et al.
Macromolecules, 47(3), 1021-1029 (2014)
Synthesis of well-defined polyethylene-based 3-miktoarm star copolymers and terpolymers
Zhang Z, et al.
Macromolecules, 49(7), 2630-2638 (2016)
Jeong Won Jang et al.
Hepatology (Baltimore, Md.), 61(6), 1809-1820 (2015-01-30)
The effect of viral suppression on long-term disease outcome after decompensation in patients with hepatitis B virus (HBV)-related cirrhosis has not been established. The aim of this study was to determine the long-term effect of antiviral therapy (AVT) in patients
Elin S Gray et al.
Oncotarget, 6(39), 42008-42018 (2015-11-03)
Repeat tumor biopsies to study genomic changes during therapy are difficult, invasive and data are confounded by tumoral heterogeneity. The analysis of circulating tumor DNA (ctDNA) can provide a non-invasive approach to assess prognosis and the genetic evolution of tumors
Santiago Palacio et al.
International journal of stroke : official journal of the International Stroke Society, 10(5), 686-691 (2013-05-23)
It remains controversial whether dual antiplatelet therapy reduces stroke more than aspirin alone. We aimed to assess the effects of adding clopidogrel to aspirin on the occurrence of stroke and major haemorrhage in patients with vascular disease. Meta-analysis of published

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