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HPLC Analysis of Spice Cannabinoids on Ascentis® Express C18

HPLC Analysis of Spice Cannabinoids on Ascentis® Express C18 application for HPLC

CONDITIONS

column

Ascentis Express C18, 10 cm x 2.1 mm I.D., 2.7 μm particles (53823-U)

mobile phase

[A] 5 mM ammonium formate water; [B] 5 mM ammonium formate (95:5, acetonitrile:water)

gradient

68 to 100% B in 8 min; held at 100% B for 2 min

flow rate

0.6 mL/min

pressure

4351 psi (300 bar)

column temp.

30 °C

detector

UV, 265 nm

injection

3 μL

Description

Analysis Note

Synthetic cannabinoids (e.g. "Spice") are a type of designer drug used to get a cannabis-type high. New synthetic cannabinoids are continually being introduced as suppliers tweak the molecular structures. The ability to rapidly and reliably identify the continually changing population of these compounds in the blood or urine suspected users is a significant analytical challenge facing forensic chemists. Here is shown the selectivity provided by C18 phase chemistry on an Ascentis Express C18 column with UV detection. Cerilliant CRMs provided reliable identification and quantification.

Legal Information

Ascentis is a registered trademark of Merck KGaA, Darmstadt, Germany