561029

3,5-Difluorophenylmagnesium bromide solution

0.5 M in THF

• Synonym(s): Bromo(3,5-difluorophenyl)magnesium
• Linear Formula: F₂C₆H₃MgBr
• CAS Number: 62351-47-7
• Molecular Weight: 217.29
• MDL number: MFCD00672005
• UNSPSC Code: 12352103
• PubChem Substance ID: 24879909
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Grignard Reaction
• concentration: 0.5 M in THF
• bp: 65 °C
• density: 0.971 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: Fc1cc(F)cc([Mg]Br)c1
• InChI: 1S/C6H3F2.BrH.Mg/c7-5-2-1-3-6(8)4-5;;/h2-4H;1H;/q;;+1/p-1
• InChI key: CURGXPMIRCWEDB-UHFFFAOYSA-M

Description

Application

3,5-Difluorophenylmagnesium bromide can be used:

• As a starting material in the synthesis of cis-2-phenyl-1-amino-cyclopentanes as AMPA receptor potentiators.
• To prepare copper(I) complexes, which are used as luminescent guest molecules in organic light-emitting diodes (OLEDs).
• As an intermediate in the synthesis of 2-aminoethylbenzofuran H₃ receptor antagonists.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• Pictograms: GHS02,GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H302,H319,H335,H351
• Precautionary Statements: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 1.4 °F - closed cup
• Flash Point(C): -17 °C - closed cup