Skip to Content
Merck
  • Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.

Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media.

Chemical communications (Cambridge, England) (2002-07-19)
Steven V Ley, Chandrashekar Ramarao, Richard S Gordon, Andrew B Holmes, Angus J Morrison, Ian F McConvey, Ian M Shirley, Stephen C Smith, Martin D Smith
PMID12122701
ABSTRACT

Palladium(II) acetate microencapsulated in polyurea (MC-[Pd]) is an economical and versatile heterogeneous catalyst for a range of phosphine-free cross-coupling reactions in both conventional solvents and supercritical carbon dioxide (scCO2); the catalyst can be recovered by a simple filtration and recycled up to four times.

MATERIALS
Product Number
Brand
Product Description
520764
Sigma-Aldrich
Palladium(II) acetate, ≥99.9% trace metals basis
644706
Sigma-Aldrich
Pd EnCat® TPP30, extent of labeling: 0.4 mmol/g Pd loading, TPP 0.8, Pd 1.0
644692
Sigma-Aldrich
Pd EnCat® TOTP30, extent of labeling: 0.4 mmol/g Pd loading, TOTP 0.5, Pd 1.0
644714
Sigma-Aldrich
Pd EnCat® 30, extent of labeling: 0.4 mmol/g Pd loading
644722
Sigma-Aldrich
Pd EnCat® 40, extent of labeling: 0.4 mmol/g Pd loading