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Dynamical (e,2e) studies of tetrahydrofurfuryl alcohol.

The Journal of chemical physics (2012-07-05)
S M Bellm, J D Builth-Williams, D B Jones, Hari Chaluvadi, D H Madison, C G Ning, F Wang, X G Ma, B Lohmann, M J Brunger
ABSTRACT

Cross section data for electron scattering from DNA are important for modelling radiation damage in biological systems. Triply differential cross sections for the electron impact ionization of the highest occupied outer valence orbital of tetrahydrofurfuryl alcohol, which can be considered as an analogue to the deoxyribose backbone molecule in DNA, have been measured using the (e,2e) technique. The measurements have been performed with coplanar asymmetric kinematics at an incident electron energy of 250 eV, an ejected electron energy of 20 eV, and at scattered electron angles of -5°, -10°, and -15°. Experimental results are compared with corresponding theoretical calculations performed using the molecular 3-body distorted wave model. Some important differences are observed between the experiment and calculations.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Tetrahydrofurfuryl alcohol, 98%
Sigma-Aldrich
Tetrahydrofurfuryl alcohol, 99%
Sigma-Aldrich
Tetrahydrofurfuryl alcohol, ≥98%
Sigma-Aldrich
(R)-Tetrahydrofurfuryl alcohol, ≥98.0% (sum of enantiomers, GC)