- Highly chemoselective Pd-C catalytic hydrodechlorination leading to the highly efficient N-debenzylation of benzylamines.
Highly chemoselective Pd-C catalytic hydrodechlorination leading to the highly efficient N-debenzylation of benzylamines.
The Journal of organic chemistry (2009-06-19)
Chuanjie Cheng, Jianwei Sun, Lixin Xing, Jimin Xu, Xinyan Wang, Yuefei Hu
PMID19534475
ABSTRACT
In the presence of 1,1,2-trichloroethane, a novel procedure for the Pd-C catalytic N-debenzylation of benzylamines was established. The method proceeded in a synergistic catalytic system and directly gave the products as crystal amine hydrochlorides in practically quantitative yields.
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