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680974

Sigma-Aldrich

3,4,5-Trimethoxyphenylmagnesium bromide solution

0.5 M in THF

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About This Item

Linear Formula:
(CH3O)3C6H2MgBr
CAS Number:
133095-91-7
Molecular Weight:
271.39
MDL number:
MFCD08064087
UNSPSC Code:
12352103
PubChem Substance ID:
24885606
NACRES:
NA.22

reaction suitability

reaction type: Grignard Reaction

Quality Level

100

concentration

0.5 M in THF

density

0.979 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

COc1cc([Mg]Br)cc(OC)c1OC

InChI

1S/C9H11O3.BrH.Mg/c1-10-7-5-4-6-8(11-2)9(7)12-3;;/h5-6H,1-3H3;1H;/q;;+1/p-1

InChI key

YWBLTWDGWZPYLJ-UHFFFAOYSA-M

Other Notes

Storage below 25 degrees C may cause the formation of crystalline magnesium salts. Moving the container to a warm location and occasional gentle swirling should redissolve the solid.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Statements

H225,H314,H351

Hazard Classifications

Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

EUH014,EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

<-4.0 °F - closed cup

Flash Point(C)

< -20 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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