Recent advances in homogeneous nickel catalysis.

Recent advances in homogeneous nickel catalysis.

Nature (2014-05-16)

Sarah Z Tasker, Eric A Standley, Timothy F Jamison

ABSTRACT

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.

MATERIALS

Product Number

Brand

Product Description

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

GF88726168

Nickel, foil, light tested, 25x25mm, thickness 0.009mm, 99.95%

901166

Sigma-Aldrich

cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride

900941

Sigma-Aldrich

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II), ≥95%

900944

Sigma-Aldrich

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II), ≥95%

GF66058612

Nickel, foil, 10mm disks, thickness 0.025mm, 99.9%

GF45284081

Nickel, foil, not light tested, 100x100mm, thickness 0.004mm, hard, 99%

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

GF49340336

Nickel, foil, 8mm disks, thickness 0.0025mm, 99.95%

GF46969587

Nickel, wire reel, 5m, diameter 0.5mm, as drawn, 99%

GF37232489

Nickel, tube, 1000mm, outside diameter 0.65mm, inside diameter 0.384mm, wall thickness 0.133mm, as drawn, 99.5%

GF46693109

Nickel, foil, 0.5m coil, thickness 0.0075mm, 99.95%

GF87671784

Nickel, foil, light tested, 300x300mm, thickness 0.015mm, 99.9%

GF86176963

Nickel, foil, light tested, 100x100mm, thickness 0.025mm, 99.9%

GF89307063

Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%

GF85861042

Nickel, foil, 0.5m coil, thickness 0.125mm, annealed, 99%

GF57292005

Nickel, foil, 0.5m coil, thickness 0.005mm, as rolled, 99.9%

GF57012421

Nickel, foil, 50x50mm, thickness 0.3mm, as rolled, 99.999%

GF42729330

Nickel, foil, 10mm disks, thickness 0.025mm, as rolled, 99.99+%

GF98554078

Nickel, tube, 500mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF62301305

Nickel, tube, 500mm, outside diameter 2.5mm, inside diameter 2mm, wall thickness 0.25mm, hard, 99.5%

GF03085321

Nickel, foil, 10mm disks, thickness 0.005mm, as rolled, 99.9%

GF46831664

Nickel, rod, 1000mm, diameter 2.0mm, 99.99+%

GF07235131

Nickel, mesh, 240x240mm, nominal aperture 0.43mm, thickness 0.004mm, wire diameter 0.067mm, 51 wires/inch, open area 75%, electro-formed mesh, 99.9%

GF25500079

Nickel, foil, 2m coil, thickness 0.5mm, annealed, 99.98%

GF33286282

Nickel, foil, 50x50mm, thickness 2.0mm, annealed, 99%