Adding Amorphous Content to Highly Crystalline Polymer Nanowire Solar Cells Increases Performance.

Polymer solar cells are fabricated with systematic variation of the phase purity. Photovoltaic tests demonstrate that devices with ca. 10% of mixed phases outperform pure-phase devices. Photophysical studies reveal the effects of mixed phase on charge generation and recombination. These results show a promising strategy for the optimization of organic electronic materials.