- Lewis acid double metal cyanide catalysts for hydroamination of phenylacetylene.
Lewis acid double metal cyanide catalysts for hydroamination of phenylacetylene.
Chemical communications (Cambridge, England) (2011-03-08)
Annelies Peeters, Pieterjan Valvekens, Frederik Vermoortele, Rob Ameloot, Christine Kirschhock, Dirk De Vos
PMID21380422
摘要
Double metal cyanides (DMCs) are highly active recyclable heterogeneous catalysts for hydroamination of phenylacetylene with 4-isopropylaniline. The best hydroamination yields are obtained with Zn-Co DMCs, especially if the particle size is decreased by a reverse emulsion synthesis technique.
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