- A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state.
A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state.
Chemical communications (Cambridge, England) (2012-08-22)
Lena Arnold, Martin Baumgarten, Klaus Müllen
PMID22908132
摘要
Carbazole-containing porphyrinoid was synthesised for the first time via Suzuki-Miyaura cross-coupling reaction. Oxidation with MnO(2) yielded its porphyrin-state featuring macrocyclic aromaticity in exchange for the loss of the resonance energies of the benzene rings.