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Merck

319953

Sigma-Aldrich

≥99.0%, ACS reagent

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About This Item

经验公式(希尔记法):
C6H6
CAS号:
分子量:
78.11
Beilstein:
969212
EC號碼:
MDL號碼:
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent

品質等級

蒸汽密度

2.77 (vs air)

蒸汽壓力

166 mmHg ( 37.7 °C)
74.6 mmHg ( 20 °C)

化驗

≥99.0%

形狀

liquid

自燃溫度

1043 °F

expl. lim.

8 %

雜質

H2SO4, passes test (darkened)
thiophene, passes test (limit ∼1ppm)
≤0.005% S compounds
≤0.05% water (Karl Fischer)

蒸發殘留物

≤0.001%

顏色

APHA: ≤10

折射率

n20/D 1.501 (lit.)

bp

80 °C (lit.)

mp

5.5 °C (lit.)

密度

0.874 g/mL at 25 °C (lit.)

SMILES 字串

c1ccccc1

InChI

1S/C6H6/c1-2-4-6-5-3-1/h1-6H

InChI 密鑰

UHOVQNZJYSORNB-UHFFFAOYSA-N

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一般說明

苯是一种单环芳香族化合物,在化学反应中用作溶剂。它是燃料、橡胶和塑料制品、洗涤剂、杀虫剂和药品的重要原料。

應用

苯可作为溶剂用于:
  • 溴化乙烯与苯乙烯的反应,以合成功能化 1,3-二烯。
  • 通过镓催化还原内酯化将 γ-酮酸转化为 γ-内酯衍生物。
  • 以磷腈为碱进行苯乙烯和 1,3-丁二烯的阴离子聚合。

訊號詞

Danger

危險分類

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 1A - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 1B - Skin Irrit. 2 - STOT RE 1

標靶器官

Blood

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

12.2 °F

閃點(°C)

-11 °C


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Cliona M McHale et al.
Carcinogenesis, 33(2), 240-252 (2011-12-15)
Benzene causes acute myeloid leukemia and probably other hematological malignancies. As benzene also causes hematotoxicity even in workers exposed to levels below the US permissible occupational exposure limit of 1 part per million, further assessment of the health risks associated
Jelle Vlaanderen et al.
Environmental health perspectives, 119(2), 159-167 (2010-10-01)
The use of occupational cohort studies to assess the association of benzene and lymphoma is complicated by problems with exposure misclassification, outcome classification, and low statistical power. We performed meta-analyses of occupational cohort studies for five different lymphoma categories: Hodgkin
Deborah C Glass et al.
Occupational and environmental medicine, 71(4), 266-274 (2014-02-18)
Benzene exposure has been associated with increased risk of leukaemia and myelodysplastic syndrome. Existing studies are sparse for other lymphohaematopoietic cancer subtypes, such as myeloproliferative disease (MPD) and the related chronic myeloid leukaemia (CML). We pooled data from three petroleum
David Galbraith et al.
Critical reviews in toxicology, 40 Suppl 2, 1-46 (2010-10-14)
Over the last century, benzene has been a well-studied chemical, with some acute and chronic exposures being directly associated with observed hematologic effects in humans and animals. Chronic heavy exposures to benzene have also been associated with acute myelogenous leukemia
Scott M Arnold et al.
Critical reviews in toxicology, 43(2), 119-153 (2013-01-26)
Abstract A framework of "Common Criteria" (i.e. a series of questions) has been developed to inform the use and evaluation of biomonitoring data in the context of human exposure and risk assessment. The data-rich chemical benzene was selected for use

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