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![[2-氧代-2-(环己基-d11)乙基]磷酸二甲酯 98 atom % D](/deepweb/assets/sigmaaldrich/product/structures/345/496/c8378259-2b5e-46e4-b405-0db89138e20f/640/c8378259-2b5e-46e4-b405-0db89138e20f.png)
形狀
solid
反應適用性
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
mp
84-85 °C
儲存溫度
−20°C
InChI
1S/C10H13NOS/c1-9(12)11-7-8-13-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,11,12)
InChI 密鑰
RSOVUTMFSIKQHH-UHFFFAOYSA-N
應用
N-(2-(Phenylthio)ethyl)acetamide is a C-H activation ligand developed by the Yu Group for the Pd-catalyzed olefination/lactonization of C(sp3)-H bonds of free carboxylic acids.
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Zhe Zhuang et al.
Journal of the American Chemical Society, 140(32), 10363-10367 (2018-07-22)
An acetyl-protected aminoethyl phenyl thioether has been developed to promote C(sp3)-H activation. Significant ligand enhancement is demonstrated by the realization of the first Pd(II)-catalyzed olefination of C(sp3)-H bonds of free carboxylic acids without using an auxiliary. Subsequent lactonization of the
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