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743003

Sigma-Aldrich

2-过氧化丁酮

technical

别名:

甲基乙基酮过氧化物, 过氧化甲乙酮

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About This Item

线性分子式:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS号:
1338-23-4
分子量:
210.22
Beilstein:
1759757
MDL號碼:
MFCD00042641
分類程式碼代碼:
12352120
PubChem物質ID:
329765606
NACRES:
NA.22

等級

technical

形狀

liquid

包含

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

反應適用性

reagent type: oxidant

折射率

n20/D 1.432

密度

1.053 g/mL at 20 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI 密鑰

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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應用

反应物用于：
  • 过氧化甲乙酮绝热失控反应的研究
  • 磨料溶出方波伏安法测定考古玻璃中的金属离子
  • 过氧化氢和过氧化氢清除物质的光子发射成像
  • 亚磷酰胺法合成寡核苷酸
  • 核苷亚磷酸酯氧化成磷酸盐
  • 人血浆谷胱甘肽过氧化物酶作为氢过氧化物酶还原催化剂的比较

乙醇-水体系中固定化血红蛋白直接电化学催化的分析物

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

儲存類別代碼

5.2 - Organic peroxides and self-reacting hazardous materials

水污染物質分類（WGK）

WGK 1

閃點（°F）

132.8 °F - closed cup

閃點（°C）

56 °C - closed cup

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F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
M Ando et al.
Chemico-biological interactions, 55(3), 317-326 (1985-11-01)
The effect of dietary vitamin E on in vivo and in vitro damage by methyl ethyl ketone peroxide (MEKP) to cytochrome P-450 and its associated enzymatic activity was studied. In vivo, MEKP damaged microsomal cytochrome P-450 and cytochrome P-450-mediated peroxidases
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
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