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Merck
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文件

370622

Sigma-Aldrich

4-(三氟甲氧基)溴苄

97%

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About This Item

线性分子式:
CF3OC6H4CH2Br
CAS号:
50824-05-0
分子量:
255.03
MDL號碼:
MFCD00061238
分類程式碼代碼:
12352100
PubChem物質ID:
24863081
NACRES:
NA.22

化驗

97%

形狀

liquid

折射率

n20/D 1.48 (lit.)

bp

82-84 °C/10 mmHg (lit.)

密度

1.594 g/mL at 25 °C (lit.)

SMILES 字串

FC(F)(F)Oc1ccc(CBr)cc1

InChI

1S/C8H6BrF3O/c9-5-6-1-3-7(4-2-6)13-8(10,11)12/h1-4H,5H2

InChI 密鑰

JDNPUJCKXLOHOW-UHFFFAOYSA-N

相关类别

一般說明

Polymerizations of 4-(trifluoromethoxy)benzyl bromide, via Friedel-Crafts polymerization using aluminum chloride as a catalyst has been reported.

應用

4-(Trifluoromethoxy)benzyl bromide may be used in the synthesis of bioreductive drug, (6S)-2-nitro-6-{[4-(trifluoromethoxy)benzyl]oxy}-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine (PA-824).

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

201.2 °F - closed cup

閃點（°C）

94 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Andrew M Thompson et al.
Journal of medicinal chemistry, 52(3), 637-645 (2008-12-23)
The nitroimidazooxazine S-1 (PA-824) is a new class of bioreductive drug for tuberculosis. A series of related bicyclic nitroheterocycles was synthesized, designed to have a wide range of one-electron reduction potentials E(1) (from -570 to -338 mV, compared with -534
Synthesis and properties of fluorine-containing poly (arylenemethylene) s as new heat resistant denatured phenolic resins.
Nemoto T, et al.
Polymer Journal, 40(7), 622-628 (2008)

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