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蒸汽壓力
0.27 psi ( 54 °C)
品質等級
化驗
≥99.99% trace metals basis
形狀
liquid
折射率
n20/D 1.697 (lit.)
bp
175 °C (lit.)
mp
−41.5 °C (lit.)
密度
2.88 g/mL at 20 °C (lit.)
SMILES 字串
BrP(Br)Br
InChI
1S/Br3P/c1-4(2)3
InChI 密鑰
IPNPIHIZVLFAFP-UHFFFAOYSA-N
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一般說明
Phosphorus tribromide (PBr3) is a phosphorus halide that can be used as a reactive phosphorylating agent for the formation of multifunctional thiophenes.
應用
PBr3 can be used as an acceptor molecule in the formation of donor-acceptor complexes. It can also be used in the phosphorylation of arylphospholes which can further be utilized in the synthesis of phosphonic amides.
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 1
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Phosphorylation of 2-(3-methyl-1, 3-diazabuten-1-yl)-3-ethoxycarbonylthiophenes with phosphorus (III) halides
Pinchuk AM, et al.
Heteroatom Chem., 12(7), 641-651 (2001)
Site-selective phosphorylation of arylphospholes through reaction with phosphorus tribromide
Keglevich G, et al.
Journal of Organometallic Chemistry, 643(11), 32-38 (2002)
Donor-acceptor complexes between organoamines and phosphorus tribromide
Muller G, et al.
Zeitschrift fur Naturforschung B, 56(11), 1163-1171 (2001)
Andrey S Mereshchenko et al.
Nature chemistry, 7(7), 562-568 (2015-06-24)
'Roaming' is a new and unusual class of reaction mechanism that has recently been discovered in unimolecular dissociation reactions of isolated molecules in the gas phase. It is characterized by frustrated bond cleavage, after which the two incipient fragments 'roam'
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