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161810

Sigma-Aldrich

5-氯-1,3,3-三甲基-2-亚甲基吲哚啉

technical grade, 95%

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About This Item

经验公式（希尔记法）:
C12H14ClN
CAS号:
6872-17-9
分子量:
207.70
EC號碼:
229-972-6
MDL號碼:
MFCD00005814
分類程式碼代碼:
12352100
PubChem物質ID:
24849955
NACRES:
NA.22

等級

technical grade

品質等級

100

化驗

95%

形狀

liquid

折射率

n20/D 1.594 (lit.)

密度

1.083 g/mL at 25 °C (lit.)

SMILES 字串

CN1C(=C)C(C)(C)c2cc(Cl)ccc12

InChI

1S/C12H14ClN/c1-8-12(2,3)10-7-9(13)5-6-11(10)14(8)4/h5-7H,1H2,2-4H3

InChI 密鑰

VDMXGJJMPKAYQP-UHFFFAOYSA-N

相关类别

一般說明

5-Chloro-2-methylene-1,3,3-trimethylindoline undergoes regiospecific 1,3-dipolar cycloaddition reaction with arylnitriloxydes and N-phenylarylnitrilimines.

應用

5-Chloro-2-methylene-1,3,3-trimethylindoline was used in the synthesis of 5′,6-dichloro-1′,3′,3′-trimethyl­spiro­[2H-1-benzopyran-2,2′-indoline].

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315 - H319 - H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F - closed cup

閃點（°C）

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Nameer Alhashimy et al.
Acta crystallographica. Section E, Structure reports online, 64(Pt 8), o1430-o1431 (2008-01-01)
In the crystal structure of the title compound, C(19)H(17)Cl(2)NO, the indoline and benzopyran ring systems are approximately perpendicular to each other. The indoline ring is in an envelope conformation with the spiro C atom as the flap. The N atom
Naoual Laghrib et al.
Acta crystallographica. Section E, Structure reports online, 65(Pt 2), o374-o374 (2009-01-01)
Two diastereoisomers of the title compound, C(25)H(26)N(2)O, have been prepared by cyclo-addition between 1,3,3-trimethyl-2-methyl-eneindoline and C-phenyl-N-phenyl-nitrone. The stereochemistry of the major diastereoisomer, viz. S,R/R,S, is confirmed by the X-ray analysis. The oxazole and the pyrole rings have envelope conformations. The

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