化驗
99%
形狀
liquid
折射率
n20/D 1.576 (lit.)
bp
196 °C (lit.)
密度
1.63 g/mL at 25 °C (lit.)
SMILES 字串
Clc1cccc(Br)c1
InChI
1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H
InChI 密鑰
JRGGUPZKKTVKOV-UHFFFAOYSA-N
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一般說明
1-溴-3-氯苯与 i -PrMgCl-LiCl 在 THF 中 0°C 下发生溴-镁交换反应，并被吸电子取代基强烈加速 。它被作为测试底物，用于研究以 K 4 [Fe (CN) 6 ] 为氰基源，在各种卤代芳烃氰化反应中使用新型催化系统的应用 。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
176.0 °F - closed cup
閃點（°C）
80 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
An efficient palladium catalytic system for microwave assisted cyanation of aryl halides.
Hajipour AR, et al.
Journal of Organometallic Chemistry, 696(4), 819-824 (2011)
Lei Shi et al.
The Journal of organic chemistry, 74(7), 2760-2764 (2009-03-14)
Competition experiments have been performed to determine the relative reactivities of substituted bromobenzenes, bromonaphthalenes, and 9-bromoanthracene toward i-PrMgCl x LiCl in THF at 0 degrees C. The rates of the bromine-magnesium exchange reactions are accelerated by electron-acceptor substituents, the activating
Silvina C Pérez et al.
Solid state nuclear magnetic resonance, 87, 18-23 (2017-07-01)
A simple model to explain the NQR lineshape in solids with orientational disorder or substitutional disorder is presented. The particular case of m-chlorobromobenzene is studied. It is based on the assumption that Bromine atoms, of m-chlorobromobenzene molecules, behave as point
K Schümann et al.
European journal of clinical investigation, 34(4), 275-282 (2004-04-17)
Iron regulatory protein 1 (IRP1), a post-transcriptional regulator of iron metabolism, is activated in the duodenum of iron-deficient animals, which is associated with increased iron absorption. In cell cultures IRP1 was also activated by iron-independent signals, such as H(2)O(2). Here
Nicholas C Pflug et al.
Environmental science & technology, 53(9), 4813-4822 (2019-03-27)
Anilines have been shown to be especially susceptible to single-electron oxidation by excited triplet-state photosensitizers (3sens*), and thus, are good potential candidates to probe the oxidative properties of triplet-state chromophoric dissolved organic matter (3CDOM*). However, steady-state experiments tend to underestimate
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