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  • Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn(III)-substituted trilacunary Keggin tungstosilicate.

Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn(III)-substituted trilacunary Keggin tungstosilicate.

Dalton transactions (Cambridge, England : 2003) (2013-02-14)
Denys Shevchenko, Ping Huang, Volodymyr V Bon, Magnus F Anderlund, Vladimir N Kokozay, Stenbjörn Styring, Anders Thapper
ABSTRACT

A rare example of a "monomeric" triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Tungsten, foil, thickness 0.25 mm, ≥99.9% trace metals basis
Sigma-Aldrich
Tungsten, wire, diam. 1.0 mm, 99.99% trace metals basis
Sigma-Aldrich
Tungsten, foil, thickness 0.127 mm, ≥99.9% trace metals basis
Sigma-Aldrich
Tungsten, wire, diam. 0.5 mm, ≥99.9% trace metals basis
Sigma-Aldrich
Tungsten, foil, thickness 0.5 mm, ≥99.9% trace metals basis
Sigma-Aldrich
Tungsten, wire, diam. 0.25 mm, ≥99.9% trace metals basis