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31627

Sigma-Aldrich

Carbon disulfide

suitable for IR spectroscopy, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.9% (GC)

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About This Item

Empirical Formula (Hill Notation):
CS2
CAS Number:
75-15-0
Molecular Weight:
76.14
Beilstein:
1098293
EC Number:
200-843-6
MDL number:
MFCD00011321
UNSPSC Code:
12352100
PubChem Substance ID:
329753851
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

100

Agency

reag. Ph. Eur.

vapor density

2.67 (vs air)

vapor pressure

5.83 psi

Assay

≥99.9% (GC)

form

liquid

autoignition temp.

212 °F

expl. lim.

50 %

technique(s)

IR spectroscopy: suitable

impurities

≤0.0001% H2S + foreign org. S-comp.
≤0.001% benzene
≤0.001% non-volatile matter
≤0.01% water (Karl Fischer)

refractive index

n20/D 1.627 (lit.)

bp

46 °C (lit.)

mp

−112-−111 °C (lit.)

density

1.266 g/mL at 25 °C (lit.)

anion traces

sulfate (SO42-): ≤2.5 mg/kg
sulfite (SO32-): ≤10 mg/kg

SMILES string

S=C=S

InChI

1S/CS2/c2-1-3

InChI key

QGJOPFRUJISHPQ-UHFFFAOYSA-N

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General description

Carbon disulfide is a sulfur containing gas. Its natural and anthropogenic sources of emissions in earth atmosphere has been investigated. Its lifetime in atmosphere has been proposed to be around 12 days. It is a non-polar solvent.

Application

Carbon disulfide may be used in the preparation of dibenzyl trithiocarbonate, a RAFT (reversible addition-fragmentation transfer) chain-transfer agent (CTA). It may be employed as solvent in the preparation of benzyl chlorodithioformate.

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1

Target Organs

Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-22.0 °F - closed cup

Flash Point(C)

-30 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Charles-André Fustin et al.
Langmuir : the ACS journal of surfaces and colloids, 22(15), 6690-6695 (2006-07-13)
We report on a simple procedure to tune the hydrophilicity of hybrid gold nanoparticles. The nanoparticles have been prepared in the core of a poly(ethylene glycol)-block-poly(epsilon-caprolactone) (PEG-b-PCL) five-arm star block copolymer. A hydrophilic corona was then added to these hybrid
Global sources, lifetimes and mass balances of carbonyl sulfide (OCS) and carbon disulfide (CS2) in the earth's atmosphere.
Khalil MAK and Rasmussen RA.
Atmospheric Environment, 18(9), 1805-1813 (1984)
The mass budgets of carbonyl sulfide, dimethyl sulfide, carbon disulfide and hydrogen sulfide.
Watts SF.
Atmospheric Environment, 34(5), 761-779 (2000)
C60: a new form of carbon.
Kratschmer W, et al.
Nature, 347(6291), 354-358 (1990)
Strongly electron deficient sulfonyldithioformate based RAFT agents for hetero Diels-Alder conjugation: Computational design and experimental evaluation.
Nebhani L, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 47(22), 6053-6053 (2009)
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