Skip to Content
Merck
All Photos(1)

Documents

293911

Sigma-Aldrich

2-Hexyne

99%

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CH3CH2CH2C≡CCH3
CAS Number:
Molecular Weight:
82.14
Beilstein:
1731542
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

refractive index

n20/D 1.414 (lit.)

bp

84-85 °C (lit.)

density

0.731 g/mL at 25 °C (lit.)

SMILES string

CCCC#CC

InChI

1S/C6H10/c1-3-5-6-4-2/h3,5H2,1-2H3

InChI key

MELUCTCJOARQQG-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Pd/SiO2 modified with ionic liquid catalyzed lead free stereoselective hydrogenation of 2-hexyne has been reported. Polymerization of 2-hexyne in toluene catalyzed by MoCl5.Ph4Sn and WCl6.Ph4Sn has been reported. Mechanism of hydrogenation of 2-hexyne in solution on selective and unselective bulk Pd has been investigated. Lanthanum-catalyzed dimerization of 2-hexyne has been reported.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

12.2 °F - closed cup

Flash Point(C)

-11 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Mechanism of 2-hexyne hydrogenation on heterogeneous palladium.
Ulan JG and Maier WF.
J. Mol. Catal., 54(2), 243-261 (1989)
Frederick Schwab et al.
Chemical communications (Cambridge, England), 50(72), 10406-10408 (2014-07-30)
A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst
Polymerization of 2-hexyne and higher 2-alkynes catalyzed by MoCl5.Ph4Sn and WCl6.Ph4Sn .
Higashimura T, et al.
Macromolecules, 15(2), 234-238 (1982)
Organolanthanide-catalyzed cyclodimerizations of disubstituted alkynes.
Heeres HJ, et al.
Organometallics, 9(5), 1508-1510 (1990)
He Nan et al.
Journal of chromatography. A, 1523, 316-320 (2017-06-26)
Silver ion or argentation chromatography utilizes stationary phases containing silver ions for the separation of unsaturated compounds. In this study, a mixed-ligand silver-based ionic liquid (IL) was evaluated for the first time as a gas chromatographic (GC) stationary phase for

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service