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Aluminum-nickel alloy

purum, 50% Al basis, 50% Ni basis

Synonym(s):

Nickel-aluminum alloy, Raney®-Nickel alloy

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About This Item

CAS Number:
12635-27-7
MDL number:
MFCD00167392
UNSPSC Code:
12161600
PubChem Substance ID:
329763924
NACRES:
NA.22

Quality Level

100

grade

purum

form

powder

composition

Al, 50%
Ni, 50%

reaction suitability

core: nickel
reagent type: catalyst

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Application

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.
  • For the conversion of carbonyl compounds to hydrocarbons.
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.
  • For the synthesis of alloyed skeletal Ni catalysts.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

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Product No.
Description
Pricing

signalword

Danger

Hazard Classifications

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
STBL0821
STBK5803
STBK2618
STBJ9872
STBJ7493

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Reduction of carbonyl groups to the corresponding methylenes with Ni-Al alloy in water.
Ishimoto K, et al.
Chemical Communications (Cambridge, England), 89(4), 514-515 (2003)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
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Nickel and Nickel-based Compounds (Complexes) as a Catalyst

Nickel transition metal and its complexes can be used as a catalyst in many synthetic transformations, like oxidative addition, C-H activation, reductive elimination, oxidative cyclization, oligomerization, and in cross-coupling reactions.

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