ALD00236

Sodium N-Boc-azetidine-3-sulfinate

• Synonym(s): Sodium 1-(tert-butoxycarbonyl)azetidine-3-sulfinate
• Empirical Formula (Hill Notation): C₈H₁₄NNaO₄S
• Molecular Weight: 243.26
• MDL number: MFCD28124336
• UNSPSC Code: 12352005
• PubChem Substance ID: 329772646

Properties

• form: powder
• Quality Level: 100
• reaction suitability: reaction type: C-C Bond Formation
• mp: 172-177 °C (w/ decomp)
• storage temp.: 2-8°C
• SMILES string: O=S([O-])C1CN(C(OC(C)(C)C)=O)C1.[Na+]
• InChI: 1S/C8H15NO4S.Na/c1-8(2,3)13-7(10)9-4-6(5-9)14(11)12;/h6H,4-5H2,1-3H3,(H,11,12);/q;+1/p-1
• InChI key: KYPHAOQWDKDUAC-UHFFFAOYSA-M

Description

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Other Notes

Radical-Based Regioselective C-H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable