- pH Effects on Electrospray Ionization Efficiency.
pH Effects on Electrospray Ionization Efficiency.
Journal of the American Society for Mass Spectrometry (2016-12-15)
Jaanus Liigand, Asko Laaniste, Anneli Kruve
PMID27966175
ABSTRACT
Electrospray ionization efficiency is known to be affected by mobile phase composition. In this paper, a detailed study of analyte ionization efficiency dependence on mobile phase pH is presented. The pH effect was studied on 28 compounds with different chemical properties. Neither pK