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Hydrosilylation kinetics of silicon nanocrystals.

Chemical communications (Cambridge, England) (2013-10-29)
Wei Sun, Chenxi Qian, Melanie L Mastronardi, Muan Wei, Geoffrey A Ozin
ABSTRACT

Hydrosilylation kinetics of hydride-capped silicon nanocrystals with 1-decene are reported for the first time. In a side-by-side comparison, it is found that microwave heating has no evident acceleration effect on the hydrosilylation rate relative to conventional thermal heating.