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Merck
  • A BINOL-based chiral polyammonium receptor for highly enantioselective recognition and fluorescence sensing of (S,S)-tartaric acid in aqueous solution.

A BINOL-based chiral polyammonium receptor for highly enantioselective recognition and fluorescence sensing of (S,S)-tartaric acid in aqueous solution.

Chemical communications (Cambridge, England) (2012-09-18)
Andrea Bencini, Carmine Coluccini, Alessandra Garau, Claudia Giorgi, Vito Lippolis, Luigi Messori, Dario Pasini, Stefano Puccioni
ABSTRACT

A chiral ditopic polyammonium receptor featuring two [9]aneN(3) moieties separated by a (S)-BINOL linker is able to selectively bind and sense in water (S,S)-tartaric acid over its (R,R)/meso forms.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
L-(+)-Tartaric acid, ACS reagent, ≥99.5%
Sigma-Aldrich
L-(+)-Tartaric acid, ≥99.7%, FCC, FG
Supelco
DL-Tartaric acid, anhydrous, suitable for ion chromatography, ≥99.5% (T)