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205559

Sigma-Aldrich

Ammonium metavanadate

99%

Synonym(s):

Ammonium vanadate(V)

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About This Item

Linear Formula:
NH4VO3
CAS Number:
7803-55-6
Molecular Weight:
116.98
EC Number:
232-261-3
MDL number:
MFCD00011430
UNSPSC Code:
12352300
eCl@ss:
38180409
PubChem Substance ID:
329752014
NACRES:
NA.55

Quality Level

100

Assay

99%

form

powder, crystals or granules

pH

7 (20 °C, 5.1 g/L)

density

2.32 g/cm3 at 25 °C (lit.)

SMILES string

N.O[V](=O)=O

InChI

1S/H3N.H2O.2O.V/h1H3;1H2;;;/q;;;;+1/p-1

InChI key

YBVKNHXQSRDWAA-UHFFFAOYSA-M

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Application

Ammonium metavanadate may be employed in the following studies:
  • Preparation of various 2-substituted aryl benzimidazole derivatives.
  • Synthesis of dioxidovanadium(V) complex.
  • Preparation of vanadia modified titania (V2O5/TiO2) photo-catalysts.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 2 - STOT RE 1 Inhalation

Target Organs

Respiratory Tract

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Philani Vusumuzi Hlophe et al.
Scientific reports, 9(1), 10044-10044 (2019-07-13)
The development of heterojunctions is the current focus of the scientific community as these materials are visible light active and the staggered positioning of their band edges combats electron-hole recombination which is the downside of most photocatalysts. In this work
Ammonium Metavanadate an Efficient Catalyst for Erlenmeyer Synthesis.
Madje B, et al.
Journal of the Indian Chemical Society, 89(9), 1295-1299 (2012)
Ammonium Metavanadate as an Efficient Catalyst for the Synthesis of 2,4,5-Triaryl-1H-imidazoles.
Niralwad KS, et al.
Journal of Heterocyclic Chemistry, 48(3), 742-745 (2011)
Microwave-assisted one-pot synthesis of octahydroquinazolinone derivatives using ammonium metavanadate under solvent-free condition.
Niralwad KS, et al.
Tetrahedron Letters, 51(28), 3616-3618 (2010)
Ammonium metavanadate: an effective catalyst for synthesis of α-hydroxyphosphonates.
Sonar SS, et al.
ARKIVOC (Gainesville, FL, United States), 2, 138-148 (2009)
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