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Iron-catalyzed dehydrogenative phosphonation of N,N-dimethylanilines.

Chemical communications (Cambridge, England) (2009-10-08)
Wei Han, Armin R Ofial
ABSTRACT

Iron(II) and iron(III) salts catalyze the oxidative alpha-phosphonation of N,N-dimethylanilines with dialkyl H-phosphonates in the presence of tert-butylhydroperoxide.

MATERIALS
Product Number
Brand
Product Description

Supelco
2,6-Dimethylaniline, analytical standard
Sigma-Aldrich
2,6-Dimethylaniline, 99%
Supelco
2,6-Dimethylaniline, PESTANAL®, analytical standard