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HPLC Analysis of Benzodiazepines on Ascentis® Express Phenyl-Hexyl with Acetonitrile Mobile Phase

HPLC Analysis of Benzodiazepines on Ascentis® Express Phenyl-Hexyl with Acetonitrile Mobile Phase application for HPLC

Materiales

analytical column

Referencia del producto
Descripción
Precios

Ascentis® Express Phenyl-Hexyl, 2.7 μm HPLC Column

2.7 μm particle size, L × I.D. 5 cm × 4.6 mm

standard

Referencia del producto
Descripción
Precios

Desmethyldiazepam

analytical standard

Oxazepam solution

1 mg/mL in methanol, ampule of 1 mL, certified reference material, Cerilliant®

Alprazolam solution

1.0 mg/mL in methanol, ampule of 1 mL, certified reference material, Cerilliant®

Clonazepam solution

1.0 mg/mL in methanol, ampule of 1 mL, certified reference material, Cerilliant®

Diazepam solution

1.0 mg/mL in methanol, ampule of 1 mL, certified reference material, Cerilliant®

CONDITIONS

column

Ascentis Express Phenyl-Hexyl, 5 cm x 4.6 mm I.D., 2.7 μm particles (53348-U)

mobile phase

[A] water; [B] acetonitrile; (62:38, A:B)

flow rate

1.4 mL/min

pressure

2600 psi (179 bar)

column temp.

35 °C

detector

UV, 250 nm

injection

2 μL

sample

0.1 g/mL of each in 20% methanol

Descripción

Analysis Note

The Phenyl-Hexyl phase of the Ascentis Express product line displays the best selectivity of this sample; selectivity is markedly affected by choice of organic modifier. The application also demonstrates feasibility of fast LC with Ascentis Express by virtue of low backpressure and high efficiency.

Legal Information

Ascentis is a registered trademark of Merck KGaA, Darmstadt, Germany