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Acetylene functionalized BODIPY dyes and their application in the synthesis of activity based proteasome probes.

Bioorganic & medicinal chemistry letters (2007-09-25)
Martijn Verdoes, Ulrik Hillaert, Bogdan I Florea, Myra Sae-Heng, Martijn D P Risseeuw, Dmitri V Filippov, Gijsbert A van der Marel, Herman S Overkleeft
RESUMEN

The synthesis of three acetylene functionalized BODIPY dyes is described. These dyes are used to fluorescently modify an azido functionalized epoxomicin analogue employing the Huisgen 1,3-dipolar cycloaddition, resulting in a panel of fluorescent epoxomicin derived proteasome probes.

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6-Heptynoic acid, 90%