248940

(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

97%

• Sinónimos: (S)-(+)-1,1′-Binaphthalene-2,2′-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
• Fórmula empírica (notación de Hill): C₂₀H₁₃O₄P
• Número de CAS: 35193-64-7
• Peso molecular: 348.29
• Beilstein/REAXYS Number: 4787775
• MDL number: MFCD00010045
• UNSPSC Code: 12352005
• PubChem Substance ID: 24854963
• NACRES: NA.22

Propiedades

• assay: 97%
• form: solid
• optical activity: [α]22/D +595°, c = 1.35 in methanol
• SMILES string: OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45
• InChI: 1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
• InChI key: JEHUZVBIUCAMRZ-UHFFFAOYSA-N

Descripción

Application

Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315
• pcodes: P302 + P352
• Hazard Classifications: Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)