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62609

Sigma-Aldrich

Lithium sulfate monohydrate

puriss. p.a., ACS reagent, ≥99.0% (dried basis, T)

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About This Item

Linear Formula:
Li2SO4 · H2O
CAS Number:
10102-25-7
Molecular Weight:
127.96
EC Number:
233-820-4
MDL number:
MFCD00149766
UNSPSC Code:
12352302
PubChem Substance ID:
329759744
NACRES:
NB.24

grade

ACS reagent
puriss. p.a.

Assay

≥99.0% (dried basis, T)

form

powder or crystals

loss

13.0-15.0% loss on drying

anion traces

chloride (Cl-): ≤20 mg/kg
nitrate (NO3-): ≤10 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤0.001% (by ICP)

SMILES string

[Li+].[Li+].O.[O-]S([O-])(=O)=O

InChI

1S/2Li.H2O4S.H2O/c;;1-5(2,3)4;/h;;(H2,1,2,3,4);1H2/q2*+1;;/p-2

InChI key

RKGLUDFWIKNKMX-UHFFFAOYSA-L

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Application

Lithium sulfate monohydrate is a colorless crystalline lithium salt. Its solubility in water decreases with a rise in temperature. It can be synthesized by the dissolution of lithium carbonate in sulfuric acid. A kinetic model has been proposed to investigate the dehydration of Li2SO4.H2O. Monte-Carlo simulation of the various processes (nucleation and growth) involved in its dehydration has been evaluated. Neutron-diffraction investigations of LiSO4.H2O have been reported.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Neutron-Diffraction Study of Lithium Sulfate Monohydrate.
Smith HG, et al.
J. Chem. Phys. , 48(12), 5561-5565 (1968)
Loïc Favergeon et al.
Physical chemistry chemical physics : PCCP, 7(21), 3723-3727 (2005-12-17)
A kinetic model for the dehydration of lithium sulfate monohydrate is proposed in order to account for experimental data obtained on single crystals by thermogravimetry at 80 degrees C under fixed water vapour pressure, and by optical microscopy. This model
Eagleson M.
Concise Encyclopedia Chemistry, 605-605 (1994)

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