Skip to Content
Merck
All Photos(1)

Key Documents

More Documents

937347

Sigma-Aldrich

(AdMPhos)PdCl2

Synonym(s):

1,1′-Bis(di-1-adamantylphosphino)ferrocene

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C50H68Cl2FeP2Pd
Molecular Weight:
964.19
UNSPSC Code:
12352142
NACRES:
NA.21

form

powder

Quality Level

100

reaction suitability

reaction type: Cross Couplings

color

brown

functional group

phosphine

SMILES string

Cl[Pd]([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)([P](c8cccc8)(C9%10C[C@H]%11C[C@H](C[C@H](C%11)C%10)C9)C%12%13C[C@H]%14C[C@H](C[C@H](C%14)C%13)C%12)Cl.[Fe]

General description

(AdMPhos)PdCl2 is a symmetrical ferrocene-based Pd-catalyst. Part of the MPhos series of diphosphino-ferrocene ligands bearing bulky adamantyl groups. (AdMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling.

Application

Murahashi-Feringa Coupling (Alkyl-Li)
Kumada-Corriu coupling (Alkyl-MgX)
Negishi coupling (Alkyl-ZnX)
Suzuki–Miyaura coupling (Alkyl-B(OR2))

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service