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  • Towards 'bio-based' Nylon: conversion of gamma-valerolactone to methyl pentenoate under catalytic distillation conditions.

Towards 'bio-based' Nylon: conversion of gamma-valerolactone to methyl pentenoate under catalytic distillation conditions.

Chemical communications (Cambridge, England) (2007-08-19)
Jean-Paul Lange, Jan Z Vestering, René J Haan
ABSTRACT

Methyl pentenoate, a promising Nylon intermediate, is produced in >95% yield via the transesterification of gamma-valerolactone, a bio-based intermediate, under catalytic distillation conditions.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
γ-Valerolactone, ReagentPlus®, 99%
Sigma-Aldrich
γ-Valerolactone, ≥99%, FCC, FG
Sigma-Aldrich
γ-Valerolactone, natural, ≥95%, FG