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925454

Sigma-Aldrich

AdCyBrettPhos Pd G6 Br

Synonym(s):

AdCyBrettPhos OAC precatalyst Br

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About This Item

Empirical Formula (Hill Notation):
C46H61BrF3O2PPd
Molecular Weight:
920.27
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

SMILES string

Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C(C(OC)=CC=C2OC)=C2C(C(C(C)C)=CC(C(C)C)=C3)=C3C(C)C)(C4CCCCC4)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5

Application

AdCyBrettPhos Pd G6 Br is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

Other Notes

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Certificates of Analysis (COA)

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