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Sigma-Aldrich

Poly[9,9-bis-(2-ethylhexyl)-9H-fluorene-2,7-diyl]

light-emitting λem 409 nm (in chloroform)

Synonym(s):

Poly[9,9-di-(2′-ethylhexyl)fluorenyl-2,7-diyl]

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About This Item

CAS Number:
188201-16-3
MDL number:
MFCD03703236
UNSPSC Code:
12352103
NACRES:
NA.23

transition temp

Tg (DSC) 45 °C (onset)

solubility

THF: soluble
chloroform: soluble
toluene: soluble
xylene: soluble

λmax

374 nm

fluorescence

λex 362 nm; λem 409 nm in chloroform

General description

Poly[9,9-bis-(2-ethylhexyl)-9H-fluorene-2,7-diyl] (PFO) is a polyfluorene based conductive liquid crystalline material that can be used as a light emitting material. It forms a semiconducting layer to enhance the electroluminescence (EL) and performance of the photonic and optoelectronic devices.
Light-emitting, conjugated polymer exhibiting blue photo- and electroluminescence.

Application

Organic Semiconductor Laser Materials
PFO forms a π-conjugating polymeric system that can produce blue EL devices which include organic light emitting diodes (OLEDs), optical fibers and molecular electronic devices.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A Blue-Light-Emitting Polymer with a Rigid Backbone for Enhanced Color Stability
Park SH, et al.
Advances in Functional Materials, 17(16), 3063-3068 (2007)
Design and performance of active coupler for plastic optical fibres
Zubia J, et al.
Electronics Letters, 38(2), 65-67 (2002)
Polymer Light-emitting Diodes Based on End-capped Poly [9, 9-di-(2′ -ethylhexyl) fluorenyl-2, 7-diyl]
Zhang Q
Chin. J. Chem., 28(8), 1482-1486 (2010)
Blue polarized electroluminescence from a liquid crystalline polyfluorene
Grell M, et al.
Advanced Materials, 11(8), 671-675 (1999)
Amplified spontaneous emission spectra of poly (9, 9-dioctylfluorenyl-2, 7-diyl) under pulsed laser excitation
Ibnaouf KH
Synthetic Metals, 209, 534-543 (2015)

Articles

Organic Semiconductor Laser Materials

In this article, we demonstrate that bis-styrylbenzene derivatives show promising characteristics for very low lasing thresholds and discuss the design considerations for organic lasing molecules.

Light-Emitting Polymers

Light-Emitting Polymers

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